ChemInform Abstract: Synthesis of Silyloxy Dienes by Silylene Transfer to Divinyl Ketones: Application to the Asymmetric Synthesis of Substituted Cyclohexanes

ChemInform Abstract: Synthesis of Silyloxy Dienes by Silylene Transfer to Divinyl Ketones: Application to the Asymmetric Synthesis of Substituted Cyclohexanes

The Ag‐catalyzed treatment of divinyl ketones with the silicon compound (II) results in formation of regioisomeric silyloxy dienes whose ratio is dependent on the structure of the divinyl ketone.

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Veröffentlicht in:ChemInform 2012-08, Vol.43 (32), p.no-no
Hauptverfasser: Ventocilla, Christian C., Woerpel, K. A.
Format: Artikel
Sprache:eng
Schlagworte:
cycloaddition reactions
cyclohexane derivatives
diastereoselective syntheses
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
enantioselective syntheses (incl. cis/trans-isomerism)
organo-silicon compounds
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Beschreibung
Zusammenfassung:The Ag‐catalyzed treatment of divinyl ketones with the silicon compound (II) results in formation of regioisomeric silyloxy dienes whose ratio is dependent on the structure of the divinyl ketone.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201232189