ChemInform Abstract: Re-Evaluating the Nucleophilicity of Zinc Enolates in Alkylation Reactions

The allylic and benzylic alkylation of zinc enolates, generated by asymmetric copper‐catalyzed conjugate addition of dialkylzinc (II) towards cyclic enones (I), with various electrophiles is described.

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Veröffentlicht in:	ChemInform 2012-07, Vol.43 (31), p.no-no
Hauptverfasser:	Jarugumilli, Gopala K., Zhu, Chunyin, Cook, Silas P.
Format:	Artikel
Sprache:	eng
Schlagworte:	addition reactions diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) general (alicyclic compounds) Zinc
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description	The allylic and benzylic alkylation of zinc enolates, generated by asymmetric copper‐catalyzed conjugate addition of dialkylzinc (II) towards cyclic enones (I), with various electrophiles is described.
doi_str_mv	10.1002/chin.201231023
format	Article
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source	Wiley Online Library Journals Frontfile Complete
subjects	addition reactions diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) general (alicyclic compounds) Zinc
title	ChemInform Abstract: Re-Evaluating the Nucleophilicity of Zinc Enolates in Alkylation Reactions
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