ChemInform Abstract: Re-Evaluating the Nucleophilicity of Zinc Enolates in Alkylation Reactions

The allylic and benzylic alkylation of zinc enolates, generated by asymmetric copper‐catalyzed conjugate addition of dialkylzinc (II) towards cyclic enones (I), with various electrophiles is described.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2012-07, Vol.43 (31), p.no-no
Hauptverfasser:	Jarugumilli, Gopala K., Zhu, Chunyin, Cook, Silas P.
Format:	Artikel
Sprache:	eng
Schlagworte:	addition reactions diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) general (alicyclic compounds) Zinc
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Beschreibung
Zusammenfassung:	The allylic and benzylic alkylation of zinc enolates, generated by asymmetric copper‐catalyzed conjugate addition of dialkylzinc (II) towards cyclic enones (I), with various electrophiles is described.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201231023