ChemInform Abstract: Arbuzov-Type Reaction of Acylphosphonites and N-Alkoxycarbonylimine Cations Generated in situ with Trifluoroacetic Anhydride

ChemInform Abstract: Arbuzov-Type Reaction of Acylphosphonites and N-Alkoxycarbonylimine Cations Generated in situ with Trifluoroacetic Anhydride

The use of biscarbamates as stable synthetic equivalents of unstable aldehydes renders possible a mild and efficient access to the target compounds, which represent N‐protected phosphinic α,α′‐pseudo dipeptides.

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Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2012-07, Vol.43 (29), p.no-no
Hauptverfasser: Dmitriev, Maxim E., Ragulin, Valery V.
Format: Artikel
Sprache:eng
Schlagworte:
amino acids
amino acids, peptides
organo-phosphorus compounds
peptides
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Beschreibung
Zusammenfassung:The use of biscarbamates as stable synthetic equivalents of unstable aldehydes renders possible a mild and efficient access to the target compounds, which represent N‐protected phosphinic α,α′‐pseudo dipeptides.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201229197