ChemInform Abstract: Expedient One-Step Synthesis of Nitrogen Stilbene Analogues by Transition Metal-Free Hydroamination of Arylacetylenes with Pyrroles

ChemInform Abstract: Expedient One-Step Synthesis of Nitrogen Stilbene Analogues by Transition Metal-Free Hydroamination of Arylacetylenes with Pyrroles

The stereochemistry of the products, ranging from 100% (E) to 96% (Z), is controlled kinetically on the initial stages of the reaction and thermodynamically in the end of the process depending on the nature of substrates and the reaction conditions.

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Veröffentlicht in:ChemInform 2012-07, Vol.43 (27), p.no-no
Hauptverfasser: Dvorko, Marina Yu, Schmidt, Elena Yu, Glotova, Tatyana E., Shabalin, Dmitrii A., Ushakov, Igor' A., Kobychev, Vladimir B., Petrushenko, Konstantin B., Mikhaleva, Al'bina I., Trofimov, Boris A.
Format: Artikel
Sprache:eng
Schlagworte:
amination
amination, N‐alkylation, N‐arylation
N-alkylation
N-arylation
pyrrole derivatives
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Zusammenfassung:The stereochemistry of the products, ranging from 100% (E) to 96% (Z), is controlled kinetically on the initial stages of the reaction and thermodynamically in the end of the process depending on the nature of substrates and the reaction conditions.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201227106