ChemInform Abstract: Polyoxometalates Paneling Through {Mo2O2S2} Coordination: Cation-Directed Conformations and Chemistry of a Supramolecular Hexameric Scaffold

ChemInform Abstract: Polyoxometalates Paneling Through {Mo2O2S2} Coordination: Cation-Directed Conformations and Chemistry of a Supramolecular Hexameric Scaffold

Depending on the ionic strength and the nature of alkali cations, trivacant [AsW9O33]9‐ polyoxometalate ions (POM) and [Mo2O2S2]2+ cations (L) react to form hexameric [(POM)6L9]36‐, tetrameric [(POM)4L6]24‐, and dimeric [(POM)2L3]12‐ clusters.

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Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2012-05, Vol.43 (20), p.no-no
Hauptverfasser: Marrot, Jerome, Pilette, Marie Anne, Haouas, Mohamed, Floquet, Sebastien, Taulelle, Francis, Lopez, Xavier, Poblet, Josep M., Cadot, Emmanuel
Format: Artikel
Sprache:eng
Schlagworte:
alkali metals
arsenic
arsenic, As
molybdenum
molybdenum, Mo
structure (solids and liquids)
sulfur
sulfur, S
tungsten
tungsten, W
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Zusammenfassung:Depending on the ionic strength and the nature of alkali cations, trivacant [AsW9O33]9‐ polyoxometalate ions (POM) and [Mo2O2S2]2+ cations (L) react to form hexameric [(POM)6L9]36‐, tetrameric [(POM)4L6]24‐, and dimeric [(POM)2L3]12‐ clusters.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201220013