ChemInform Abstract: Counterion Influence on the Vibrational Wavenumbers in Ternary and Quaternary Metal Hydride Salts, A2MH6 (A: Alkali Metal, Alkaline Earth, and Lanthanides; M: Ir, Fe, Ru, Os, Pt, Mn)

ChemInform Abstract: Counterion Influence on the Vibrational Wavenumbers in Ternary and Quaternary Metal Hydride Salts, A2MH6 (A: Alkali Metal, Alkaline Earth, and Lanthanides; M: Ir, Fe, Ru, Os, Pt, Mn)

The wavenumbers of the ν3 metal—hydrogen stretching mode in the IR spectra of [MnH6]5‐, [FeH6]4‐, [RuH6]4‐, [OsH6]4‐, [IrH6]3‐, and [PtH6]2‐ linearly depend on the ionization energies of the counterions (alkali metal, alkaline earth, lanthanoid) with a separate line for each metal.

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Veröffentlicht in:ChemInform 2012-04, Vol.43 (16), p.no-no
Hauptverfasser: Gilson, Denis F. R., Moyer, Ralph O. Jr
Format: Artikel
Sprache:eng
Schlagworte:
Earth
hydrogen
hydrogen, H
IR and Raman spectra (solids and liquids)
transition metals
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Zusammenfassung:The wavenumbers of the ν3 metal—hydrogen stretching mode in the IR spectra of [MnH6]5‐, [FeH6]4‐, [RuH6]4‐, [OsH6]4‐, [IrH6]3‐, and [PtH6]2‐ linearly depend on the ionization energies of the counterions (alkali metal, alkaline earth, lanthanoid) with a separate line for each metal.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201216006