ChemInform Abstract: Use of Alkyl 2,4,6-Triisopropylbenzoates in the Asymmetric Homologation of Challenging Boronic Esters
Addition of α‐lithiated alkyl 2,4,6‐triisopropylbenzoates (I) to boronic esters (II) leads to boron‐ate complexes which rapidly undergo 1,2‐metallate rearrangement to give homologated products (III).
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| Veröffentlicht in: | ChemInform 2012-04, Vol.43 (15), p.no-no |
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| container_title | ChemInform |
| container_volume | 43 |
| creator | Larouche-Gauthier, Robin Fletcher, Catherine J. Couto, Irantzu Aggarwal, Varinder K. |
| description | Addition of α‐lithiated alkyl 2,4,6‐triisopropylbenzoates (I) to boronic esters (II) leads to boron‐ate complexes which rapidly undergo 1,2‐metallate rearrangement to give homologated products (III). |
| doi_str_mv | 10.1002/chin.201215058 |
| format | Article |
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| language | eng |
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| source | Wiley Online Library Journals |
| subjects | alcohols (benzene compounds) diastereoselective syntheses diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) enantioselective syntheses (incl. cis/trans-isomerism) |
| title | ChemInform Abstract: Use of Alkyl 2,4,6-Triisopropylbenzoates in the Asymmetric Homologation of Challenging Boronic Esters |
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