ChemInform Abstract: A New Synthesis of Alkyl (E)-(3-Dimethylamino)acrylates

The stereoselective synthesis of title compounds (III) and (VI) is achieved by reaction of Vilsmeier reagent, in situ generated from DMF and SOCl2, with ketene acetals.

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Bibliographische Detailangaben
Veröffentlicht in:	ChemInform 2012-02, Vol.43 (9), p.no-no
Hauptverfasser:	Robertson, Jeffrey M., Jones, Ian W., Kayne, Kevin M., Contreras, Cristina G., Witter, Daniel J., Bates, Robert B., Hall, H. K. Jr
Format:	Artikel
Sprache:	eng
Schlagworte:	carboxylic acid esters (acyclic compounds) e/z-selectivity (incl. e/z-isomerism)
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The stereoselective synthesis of title compounds (III) and (VI) is achieved by reaction of Vilsmeier reagent, in situ generated from DMF and SOCl2, with ketene acetals.
ISSN:	0931-7597 1522-2667
DOI:	10.1002/chin.201209055