ChemInform Abstract: Enantioselective Conjugate Allylation of Cyclic Enones

ChemInform Abstract: Enantioselective Conjugate Allylation of Cyclic Enones

Asymmetric 1,2‐allylation of cyclic enones followed by oxy‐Cope rearrangement allows convenient access to various optically active β‐allylated cyclic ketones.

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Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2012-01, Vol.43 (3), p.no-no
Hauptverfasser: Taber, Douglass F., Gerstenhaber, David A., Berry, James F.
Format: Artikel
Sprache:eng
Schlagworte:
Beta
C-C bond formation
cyclohexane derivatives
cyclopentane derivatives
diastereoselective syntheses
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
enantioselective syntheses (incl. cis/trans-isomerism)
rings with 7 or more members
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Beschreibung
Zusammenfassung:Asymmetric 1,2‐allylation of cyclic enones followed by oxy‐Cope rearrangement allows convenient access to various optically active β‐allylated cyclic ketones.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201203046