Water–acetone Media Enforced Chemoselective Synthesis of 2-substituted Pyrrole Stable Phosphorus Ylides from Reaction between Pyrrole and Acetylenic Esters in the Presence of Triphenylphosphine

Water–acetone Media Enforced Chemoselective Synthesis of 2-substituted Pyrrole Stable Phosphorus Ylides from Reaction between Pyrrole and Acetylenic Esters in the Presence of Triphenylphosphine

Pyrrole undergoes a smooth reaction with dialkyl acetylenedicarboxylates in the presence of triphenylphosphine in a mixture of water–acetone (50:50) as a solvent pathway to produce phosphorus ylides of 2-substituted pyrrole in good yield.

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Veröffentlicht in:Journal of chemical research 2007-10, Vol.2007 (10), p.566-568
Hauptverfasser: Maghsoodlou, Malek Taher, Hazeri, Nourollah, Habibi-Khorassani, Sayyed Mostafa, Moeeni, Zohreh, Marandi, Ghasem, Lashkari, Mojtaba, Ghasemzadeh, Marjan, Bijanzadeh, Hamid Reza
Format: Artikel
Sprache:eng
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Zusammenfassung:Pyrrole undergoes a smooth reaction with dialkyl acetylenedicarboxylates in the presence of triphenylphosphine in a mixture of water–acetone (50:50) as a solvent pathway to produce phosphorus ylides of 2-substituted pyrrole in good yield.
ISSN:1747-5198
2047-6507
DOI:10.3184/030823407X255560