ChemInform Abstract: Asymmetric Transfer Hydrogenation of Ketimines Using Well-Defined Iron(II)-Based Precatalysts Containing a PNNP Ligand

ChemInform Abstract: Asymmetric Transfer Hydrogenation of Ketimines Using Well-Defined Iron(II)-Based Precatalysts Containing a PNNP Ligand

N‐Phosphinoylketimines are reduced by iPrOH to the corresponding amines with 95—99% enantioselectivity at low catalyst loading of iron(II)‐complex FER.

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Bibliographische Detailangaben
Veröffentlicht in:ChemInform 2012-12, Vol.43 (52), p.no-no
Hauptverfasser: Mikhailine, Alexandre A., Maishan, Mazharul I., Morris, Robert H.
Format: Artikel
Sprache:eng
Schlagworte:
amines (benzene compounds)
diastereoselective syntheses
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)
enantioselective syntheses (incl. cis/trans-isomerism)
hydrogenation
organo-phosphorus compounds
reduction
reduction, hydrogenation
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Beschreibung
Zusammenfassung:N‐Phosphinoylketimines are reduced by iPrOH to the corresponding amines with 95—99% enantioselectivity at low catalyst loading of iron(II)‐complex FER.
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201252023