Spectroscopic Evidence for the Structure Directing Role of the Solvent in the Synthesis of Two Iron Carboxylates

Spectroscopic Evidence for the Structure Directing Role of the Solvent in the Synthesis of Two Iron Carboxylates

Crystal engineering: The synthesis of the known compounds MIL‐100(Fe) and MIL‐45(Fe) is characterized by spectroscopy. The products are obtained under identical conditions by varying the solvent from pure water to a mixture of water and acetone. The starting solution, the gel, and the final reaction...

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Veröffentlicht in:Angewandte Chemie International Edition 2012-12, Vol.51 (50), p.12490-12494
Hauptverfasser: Birsa Čelič, Tadeja, Rangus, Mojca, Lázár, Károly, Kaučič, Venčeslav, Zabukovec Logar, Nataša
Format: Artikel
Sprache:eng
Schlagworte:
crystallization
EXFAS spectroscopy
metal-organic frameworks
Moessbauer spectroscopy
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Zusammenfassung:Crystal engineering: The synthesis of the known compounds MIL‐100(Fe) and MIL‐45(Fe) is characterized by spectroscopy. The products are obtained under identical conditions by varying the solvent from pure water to a mixture of water and acetone. The starting solution, the gel, and the final reaction product were characterized by X‐ray absorption spectroscopy (see picture).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201204573