Stepwise Construction of the CrCr Quintuple Bond and Its Destruction upon Axial Coordination

Give me five! Terdentate 2,6-diamidopyridyl ligands were used to stabilize the Cr-Cr quintuple bond and have made it possible to isolate and characterize not only the Cr-Cr quintuple-bonded complex, but also the mixed-valent intermediates (Cr(I) and Cr(II)), which are important species in the format...

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Veröffentlicht in:	Angewandte Chemie International Edition 2012-07, Vol.51 (31), p.7781
Hauptverfasser:	Huang, Yu-Lun, Lu, Duan-Yen, Yu, Hsien-Cheng, Yu, Jen-Shiang K, Hsu, Chia-Wei, Kuo, Ting-Shen, Lee, Gene-Hsiang, Wang, Yu, Tsai, Yi-Chou
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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Zusammenfassung:	Give me five! Terdentate 2,6-diamidopyridyl ligands were used to stabilize the Cr-Cr quintuple bond and have made it possible to isolate and characterize not only the Cr-Cr quintuple-bonded complex, but also the mixed-valent intermediates (Cr(I) and Cr(II)), which are important species in the formation of typeI quintuple-bonded complexes.
ISSN:	1433-7851 1521-3773