ChemInform Abstract: Reaction of [alpha]-Nitroacrylates with Acetylacetone

[alpha]-Nitroacrylates (I) successfully react with acetylacetone in MeOH in the presence of MeONa to give addition products (III), which can undergo an intramolecular O-alkylation accompanied with elimination of nitrous acid [[arrow right] (IV)]. [PUBLICATION ABSTRACT]

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Veröffentlicht in:ChemInform 2012-12, Vol.43 (49), p.no
Hauptverfasser: Baichurina, L. V, Baichurin, R. I, Aboskalova, N. I, Zobacheva, M. M, Berestovitskaya, V. M
Format: Artikel
Sprache:eng
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Zusammenfassung:[alpha]-Nitroacrylates (I) successfully react with acetylacetone in MeOH in the presence of MeONa to give addition products (III), which can undergo an intramolecular O-alkylation accompanied with elimination of nitrous acid [[arrow right] (IV)]. [PUBLICATION ABSTRACT]
ISSN:0931-7597
1522-2667
DOI:10.1002/chin.201249107