Cu(II)-Catalyzed Enantioselective Conjugate Reduction for the Synthesis of N-Aryl [beta]-Amino Acid Esters

Cu(II)-Catalyzed Enantioselective Conjugate Reduction for the Synthesis of N-Aryl [beta]-Amino Acid Esters

A new set of reaction conditions has been established and allowed for the first non-noble Cu(II)-catalyzed asymmetric 1,4-hydrosilylation of N-aryl [beta]-enamino esters under air to afford a selection of N-aryl [beta]-amino acid esters of moderate-to-good enantiopurities (ee up to 91%). [PUBLICATIO...

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Veröffentlicht in:Chinese journal of chemistry 2012-11, Vol.30 (11), p.2611
Hauptverfasser: Sui, Yaozong, Fang, Qiang, Li, Min, Hu, Yihu, Xia, Hongfeng, Li, Shijun, Wu, Jing
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Sprache:eng
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Zusammenfassung:A new set of reaction conditions has been established and allowed for the first non-noble Cu(II)-catalyzed asymmetric 1,4-hydrosilylation of N-aryl [beta]-enamino esters under air to afford a selection of N-aryl [beta]-amino acid esters of moderate-to-good enantiopurities (ee up to 91%). [PUBLICATION ABSTRACT]
ISSN:1001-604X
1614-7065