Sonochemically synthesized core-shell structured Au-Pd nanoparticles supported on [gamma]-Fe2O3 particles
Issue Title: Special Focus: Nanomaterials for Bio-chemical Sensors A sample of Au-Pd bimetallic nanoparticles supported on γ-Fe^sub 2^O^sub 3^ was synthesized in a sonochemically one-pot process. The structural analyses of the synthesized sample were performed by the techniques of X-ray Absorption F...
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Veröffentlicht in: | Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology 2006-12, Vol.8 (6), p.951 |
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Hauptverfasser: | , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Issue Title: Special Focus: Nanomaterials for Bio-chemical Sensors A sample of Au-Pd bimetallic nanoparticles supported on γ-Fe^sub 2^O^sub 3^ was synthesized in a sonochemically one-pot process. The structural analyses of the synthesized sample were performed by the techniques of X-ray Absorption Fine Structure (XAFS), X-ray Diffraction (XRD), Transmission Electron Microscopy (TEM) and UV-vis spectrometry. Results indicated that the synthesized sample formed a core-shell structure in which a gold core was surrounded by a thin palladium shell. The reaction rate constant for the hydrogenation of cyclohexene of the present sample showed higher value than that of Pd nanoparticles supported on γ-Fe^sub 2^O^sub 3^ and core-shell structured Au-Pd nanoparticles supported on SiO^sub 2^. The present sample is a promising catalyst material which has a high catalytic activity.[PUBLICATION ABSTRACT] |
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ISSN: | 1388-0764 1572-896X |
DOI: | 10.1007/s11051-005-9048-3 |