Sonochemically synthesized core-shell structured Au-Pd nanoparticles supported on [gamma]-Fe2O3 particles

Issue Title: Special Focus: Nanomaterials for Bio-chemical Sensors A sample of Au-Pd bimetallic nanoparticles supported on γ-Fe^sub 2^O^sub 3^ was synthesized in a sonochemically one-pot process. The structural analyses of the synthesized sample were performed by the techniques of X-ray Absorption F...

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Veröffentlicht in:Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology 2006-12, Vol.8 (6), p.951
Hauptverfasser: Nitani, Hiroaki, Yuya, Masato, Ono, Takahiro, Nakagawa, Takashi, Seino, Satoshi, Okitsu, Kenji, Mizukoshi, Yoshiteru, Emura, Shuichi, Yamamoto, Takao A
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Sprache:eng
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Zusammenfassung:Issue Title: Special Focus: Nanomaterials for Bio-chemical Sensors A sample of Au-Pd bimetallic nanoparticles supported on γ-Fe^sub 2^O^sub 3^ was synthesized in a sonochemically one-pot process. The structural analyses of the synthesized sample were performed by the techniques of X-ray Absorption Fine Structure (XAFS), X-ray Diffraction (XRD), Transmission Electron Microscopy (TEM) and UV-vis spectrometry. Results indicated that the synthesized sample formed a core-shell structure in which a gold core was surrounded by a thin palladium shell. The reaction rate constant for the hydrogenation of cyclohexene of the present sample showed higher value than that of Pd nanoparticles supported on γ-Fe^sub 2^O^sub 3^ and core-shell structured Au-Pd nanoparticles supported on SiO^sub 2^. The present sample is a promising catalyst material which has a high catalytic activity.[PUBLICATION ABSTRACT]
ISSN:1388-0764
1572-896X
DOI:10.1007/s11051-005-9048-3