Synthesis by-products from the Wacker oxidation of safrole in methanol using -benzoquinone and palladium chloride

Synthesis by-products from the Wacker oxidation of safrole in methanol using -benzoquinone and palladium chloride

This paper reports the identification of a number of by-products, which are produced during the Wacker oxidation of safrole to 3,4-methylenedioxyphenyl-2-propanone (MDP2P) using ρ-benzoquinone and palladium chloride when methanol is utilised as the solvent. Also described is the retrieval of these c...

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Veröffentlicht in:Forensic science international 2006-12, Vol.164 (2-3), p.138
Hauptverfasser: Cox, M, Klass, G
Format: Artikel
Sprache:eng
Schlagworte:
Analysis
Analytical chemistry
Chromatography
Ecstasy (Drug)
Ethanol
Forensic sciences
Gas chromatography
Laboratories
Mass spectrometry
Oxidation-reduction reaction
Vacuum distillation
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Zusammenfassung:This paper reports the identification of a number of by-products, which are produced during the Wacker oxidation of safrole to 3,4-methylenedioxyphenyl-2-propanone (MDP2P) using ρ-benzoquinone and palladium chloride when methanol is utilised as the solvent. Also described is the retrieval of these compounds from illicit samples from a clandestine laboratory, which was uncovered in South Australia in September 2003.
ISSN:0379-0738
1872-6283
DOI:10.1016/j.forsciint.2005.12.019