Multilayered Iron Complexes of [2.2]paracyclophane

Multilayered Iron Complexes of [2.2]paracyclophane

Recent syntheses of ruthenium complexes of [2.2]paracyclophane provided a highly interesting class of compounds, the multilayered transition metal complexes of cyclophanes. The present study discloses that arene-metal exchange procedures with ferrocene derivatives, effected either photochemically or...

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Veröffentlicht in:Proceedings of the National Academy of Sciences - PNAS 1981-05, Vol.78 (5), p.2657-2658
Hauptverfasser: Laganis, Evan D., Finke, R. G., Boekelheide, V.
Format: Artikel
Sprache:eng
Schlagworte:
Aluminum
Chlorides
Chromium
Coordination chemistry
Ethers
Ferrocenes
Iron
Physical Sciences: Chemistry
Polymers
Tetrahedrons
Transition metals
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Zusammenfassung:Recent syntheses of ruthenium complexes of [2.2]paracyclophane provided a highly interesting class of compounds, the multilayered transition metal complexes of cyclophanes. The present study discloses that arene-metal exchange procedures with ferrocene derivatives, effected either photochemically or by Lewis acid catalysis, are convenient methods for preparing the analogous multilayered iron complexes of [2.2]paracyclophane.
ISSN:0027-8424
1091-6490
DOI:10.1073/pnas.78.5.2657