Space-Time Thermodynamics of the Glass Transition

We consider the probability distribution for fluctuations in dynamical action and similar quantities related to dynamic heterogeneity. We argue that the so-called "glass transition" is a manifestation of low action tails in these distributions where the entropy of trajectory space is subex...

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Veröffentlicht in:Proceedings of the National Academy of Sciences - PNAS 2005-08, Vol.102 (31), p.10837-10840
Hauptverfasser: Merolle, Mauro, Garrahan, Juan P., Chandler, David
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Sprache:eng
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Zusammenfassung:We consider the probability distribution for fluctuations in dynamical action and similar quantities related to dynamic heterogeneity. We argue that the so-called "glass transition" is a manifestation of low action tails in these distributions where the entropy of trajectory space is subextensive in time. These low action tails are a consequence of dynamic heterogeneity and an indication of phase coexistence in trajectory space. The glass transition, where the system falls out of equilibrium, is then an order-disorder phenomenon in space-time occurring at a temperature Tg, which is a weak function of measurement time. We illustrate our perspective ideas with facilitated lattice models and note how these ideas apply more generally.
ISSN:0027-8424
1091-6490
DOI:10.1073/pnas.0504820102