Design of Chiral Ligands for Asymmetric Catalysis: From C2-Symmetric P,P- and N,N-Ligands to Sterically and Electronically Nonsymmetrical P,N-Ligands

Design of Chiral Ligands for Asymmetric Catalysis: From C2-Symmetric P,P- and N,N-Ligands to Sterically and Electronically Nonsymmetrical P,N-Ligands

For a long time, C2-symmetric ligands have dominated in asymmetric catalysis. More recently, nonsymmetrical modular P,N-ligands have been introduced. These ligands have been applied successfully in various metal-catalyzed reactions and, in many cases, have outperformed P,P- or N,N-ligands.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Proceedings of the National Academy of Sciences - PNAS 2004-04, Vol.101 (16), p.5723-5726
Hauptverfasser: Pfaltz, Andreas, Drury, William J., Trost, Barry M.
Format: Artikel
Sprache:eng
Schlagworte:
Acetates
Alkenes
Asymmetric Catalysis Special Feature Part II
Atoms
Catalysis
Catalysts
Hydrogenation
Ligands
Metals
Organic chemistry
Phenyls
Tetrahedrons
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:For a long time, C2-symmetric ligands have dominated in asymmetric catalysis. More recently, nonsymmetrical modular P,N-ligands have been introduced. These ligands have been applied successfully in various metal-catalyzed reactions and, in many cases, have outperformed P,P- or N,N-ligands.
ISSN:0027-8424
1091-6490
DOI:10.1073/pnas.0307152101