Mechanisms in the chlorinolysis of sulfinyl chlorides

The successful synthesis and chlorinolysis of α-mercaptodimefhyl sulfone have provided additional support for our contention that Pummerer rearrangements may occur during the chlorinolyses of α-sulfonyl sulfinyl chlorides. Further exploration of chlorinolyses of α-sulfonyl systems has uncovered the...

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Veröffentlicht in:	Canadian journal of chemistry 1984-03, Vol.62 (3), p.610-614
Hauptverfasser:	Ahern, Terence Patrick, Haley, Michael Francis, Langler, Richard Francis, Trenholm, June Ellen
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Kinetics and mechanisms Organic chemistry Reactivity and mechanisms
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Beschreibung
Zusammenfassung:	The successful synthesis and chlorinolysis of α-mercaptodimefhyl sulfone have provided additional support for our contention that Pummerer rearrangements may occur during the chlorinolyses of α-sulfonyl sulfinyl chlorides. Further exploration of chlorinolyses of α-sulfonyl systems has uncovered the first observations of CS bond cleavage during the chlorinolyses of (i) a sulfinyl chloride and (ii) a sulfinate ester.
ISSN:	0008-4042 1480-3291
DOI:	10.1139/v84-103