A synthesis of (+)-aphidicol-15-ene

A synthesis of (+)-aphidicol-15-ene

A stereospecific synthesis of (+)-aphidicol-15-ene is described. Pursuing a concept successfully applied to our total synthesis of stemarin and the stemodane diterpenoids, the C/D ring system was elaborated by functional group manipulation and rearrangement of a 6-hydroxybicyclo[2.2.2]octan-2-one sy...

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Veröffentlicht in:Canadian journal of chemistry 1984-10, Vol.62 (10), p.1930-1932
Hauptverfasser: Kelly, Ronald B, Lal, G. Sankar, Gowda, Gopala, Rej, Rabindra N
Format: Artikel
Sprache:eng
Schlagworte:
Alicyclic compounds, terpenoids, prostaglandins, steroids
Chemistry
Exact sciences and technology
Organic chemistry
Preparations and properties
Terpenoids
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Zusammenfassung:A stereospecific synthesis of (+)-aphidicol-15-ene is described. Pursuing a concept successfully applied to our total synthesis of stemarin and the stemodane diterpenoids, the C/D ring system was elaborated by functional group manipulation and rearrangement of a 6-hydroxybicyclo[2.2.2]octan-2-one system.
ISSN:0008-4042
1480-3291
DOI:10.1139/v84-331