Glucosidation shifts of allylic and benzylic alcohols in 13C NMR spectroscopy

The 13C FT NMR spectra of β‐D‐glucopyranosides (including their tetraacetates) of several secondary allylic and benzylic alcohols were compared with those of methyl β‐D‐glucopyranoside and the corresponding parent alcohols. The characeristic glucosidation shifts observed for these alcohols may be ap...

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Veröffentlicht in:	Organic Magnetic Resonance 1984-07, Vol.22 (7), p.428-430
Hauptverfasser:	Horibe, Isao, Seo, Shujiro, Yoshimura, Yohko, Tori, Kazuo
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic and molecular physics Exact sciences and technology General molecular conformation and symmetry stereochemistry Molecular properties and interactions with photons Physics Properties of molecules and molecular ions
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Zusammenfassung:	The 13C FT NMR spectra of β‐D‐glucopyranosides (including their tetraacetates) of several secondary allylic and benzylic alcohols were compared with those of methyl β‐D‐glucopyranoside and the corresponding parent alcohols. The characeristic glucosidation shifts observed for these alcohols may be applicable to the determination of the absolute configuration of the hydroxy group in these alcohols.
ISSN:	0030-4921 1097-458X
DOI:	10.1002/mrc.1270220706