Ternary charge transfer complexes. V. Complexes with thiazyl salts

Ternary charge transfer complexes. V. Complexes with thiazyl salts

Charge transfer complexes NS + MFn − *arene, where M = B, n = 4; M = P, As, or Sb, n = 6; and arene is hexamethylbenzene, mesitylene, napthalene, or 9,10-dimethylanthracene, have been prepared and characterized. The reaction of NS + MF 6 − (M = As or Sb) with highly oriented pyrolytic graphite resul...

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Veröffentlicht in:Canadian journal of chemistry 1987-06, Vol.65 (6), p.1361-1363
Hauptverfasser: Brownstein, Sydney, Louie, Brenda
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Exact sciences and technology
Inorganic chemistry and origins of life
Miscellaneous
Preparations and properties
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Zusammenfassung:Charge transfer complexes NS + MFn − *arene, where M = B, n = 4; M = P, As, or Sb, n = 6; and arene is hexamethylbenzene, mesitylene, napthalene, or 9,10-dimethylanthracene, have been prepared and characterized. The reaction of NS + MF 6 − (M = As or Sb) with highly oriented pyrolytic graphite results in graphite intercalated only with the metal fluoride anions.
ISSN:0008-4042
1480-3291
DOI:10.1139/v87-229