Transition metal carbonylates in nucleophilic aromatic substitution: II. Medium effects for substitution in 2-(pentacarbonylmanganese)-4,6-difluoro-1,3,5-triazine
Effects of counterion, solvent and solvating agents were studied for the reactions of transition metal carbonylates CpFe(CO) 2 −, (Cp = C 5H 5), Re(CO) 5 −1, Mn(CO) 5 −, CpW(CO) 3 −1, CpMo(CO) 3 − with 2-(pentacarbonylmagnanese)-4,6-difluoro-1,3,5-triazine. The observed trends substantiate the hypot...
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| Veröffentlicht in: | Journal of organometallic chemistry 1987-04, Vol.321 (3), p.371-376 |
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| container_end_page | 376 |
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| container_issue | 3 |
| container_start_page | 371 |
| container_title | Journal of organometallic chemistry |
| container_volume | 321 |
| creator | Artamkina, G.A. Mil'chenko, A.Yu Beletskaya, I.P. Reutov, O.A. |
| description | Effects of counterion, solvent and solvating agents were studied for the reactions of transition metal carbonylates CpFe(CO)
2
−, (Cp = C
5H
5), Re(CO)
5
−1, Mn(CO)
5
−, CpW(CO)
3
−1, CpMo(CO)
3
− with 2-(pentacarbonylmagnanese)-4,6-difluoro-1,3,5-triazine. The observed trends substantiate the hypothesis of enhanced reactivity of contact ion pairs as compared to solvent-separated ion pairs and free ions. |
| doi_str_mv | 10.1016/0022-328X(87)80309-1 |
| format | Article |
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2
−, (Cp = C
5H
5), Re(CO)
5
−1, Mn(CO)
5
−, CpW(CO)
3
−1, CpMo(CO)
3
− with 2-(pentacarbonylmagnanese)-4,6-difluoro-1,3,5-triazine. The observed trends substantiate the hypothesis of enhanced reactivity of contact ion pairs as compared to solvent-separated ion pairs and free ions.</description><identifier>ISSN: 0022-328X</identifier><identifier>EISSN: 1872-8561</identifier><identifier>DOI: 10.1016/0022-328X(87)80309-1</identifier><identifier>CODEN: JORCAI</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Chemistry ; Exact sciences and technology ; Inorganic chemistry and origins of life ; Kinetics and mechanism of reactions</subject><ispartof>Journal of organometallic chemistry, 1987-04, Vol.321 (3), p.371-376</ispartof><rights>1987</rights><rights>1987 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/0022-328X(87)80309-1$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=8082530$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Artamkina, G.A.</creatorcontrib><creatorcontrib>Mil'chenko, A.Yu</creatorcontrib><creatorcontrib>Beletskaya, I.P.</creatorcontrib><creatorcontrib>Reutov, O.A.</creatorcontrib><title>Transition metal carbonylates in nucleophilic aromatic substitution: II. Medium effects for substitution in 2-(pentacarbonylmanganese)-4,6-difluoro-1,3,5-triazine</title><title>Journal of organometallic chemistry</title><description>Effects of counterion, solvent and solvating agents were studied for the reactions of transition metal carbonylates CpFe(CO)
2
−, (Cp = C
5H
5), Re(CO)
5
−1, Mn(CO)
5
−, CpW(CO)
3
−1, CpMo(CO)
3
− with 2-(pentacarbonylmagnanese)-4,6-difluoro-1,3,5-triazine. The observed trends substantiate the hypothesis of enhanced reactivity of contact ion pairs as compared to solvent-separated ion pairs and free ions.</description><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>Inorganic chemistry and origins of life</subject><subject>Kinetics and mechanism of reactions</subject><issn>0022-328X</issn><issn>1872-8561</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1987</creationdate><recordtype>article</recordtype><recordid>eNpVkctKxTAQhoMoeLy8gYssXCicaC62TV0IcvByQHGj4C5M06lG2vSQpII-jk9q6w1czSy--Wf-fwjZE_xIcJEfcy4lU1I_HujiUHPFSybWyEzoQjKd5WKdzP6QTbIV4wvnXCiuZ-TjPoCPLrne0w4TtNRCqHr_1kLCSJ2nfrAt9qtn1zpLIfQdpLGJQxWTS8M0eEqXyyN6i7UbOopNgzZF2vThHzRJSXawQp_gd0UH_gk8RjxkJ_Oc1a5phz70TMzVPGMpOHh3HnfIRgNtxN2fuk0eLi_uF9fs5u5quTi_YSgymZiotM0zqblErSuFdc5Pqqq2ma7QFpWua1uAAshKkDnmuZQoVWYLq7GUsizVNtn_1l1BtNA2YzDWRbMKroPwZjTXMlN8xM6-MRxveXUYTLQOvR3th9G5qXtnBDfTY8yUuplSN7owX48xQn0CRkCFEg</recordid><startdate>19870410</startdate><enddate>19870410</enddate><creator>Artamkina, G.A.</creator><creator>Mil'chenko, A.Yu</creator><creator>Beletskaya, I.P.</creator><creator>Reutov, O.A.</creator><general>Elsevier B.V</general><general>Elsevier Science</general><scope>IQODW</scope></search><sort><creationdate>19870410</creationdate><title>Transition metal carbonylates in nucleophilic aromatic substitution: II. Medium effects for substitution in 2-(pentacarbonylmanganese)-4,6-difluoro-1,3,5-triazine</title><author>Artamkina, G.A. ; Mil'chenko, A.Yu ; Beletskaya, I.P. ; Reutov, O.A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-e152t-1b8c652802e88b3ed604bbdc58bec7b8ddc7a3aa59a26e6622e235c7c8e922993</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1987</creationdate><topic>Chemistry</topic><topic>Exact sciences and technology</topic><topic>Inorganic chemistry and origins of life</topic><topic>Kinetics and mechanism of reactions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Artamkina, G.A.</creatorcontrib><creatorcontrib>Mil'chenko, A.Yu</creatorcontrib><creatorcontrib>Beletskaya, I.P.</creatorcontrib><creatorcontrib>Reutov, O.A.</creatorcontrib><collection>Pascal-Francis</collection><jtitle>Journal of organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Artamkina, G.A.</au><au>Mil'chenko, A.Yu</au><au>Beletskaya, I.P.</au><au>Reutov, O.A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Transition metal carbonylates in nucleophilic aromatic substitution: II. Medium effects for substitution in 2-(pentacarbonylmanganese)-4,6-difluoro-1,3,5-triazine</atitle><jtitle>Journal of organometallic chemistry</jtitle><date>1987-04-10</date><risdate>1987</risdate><volume>321</volume><issue>3</issue><spage>371</spage><epage>376</epage><pages>371-376</pages><issn>0022-328X</issn><eissn>1872-8561</eissn><coden>JORCAI</coden><abstract>Effects of counterion, solvent and solvating agents were studied for the reactions of transition metal carbonylates CpFe(CO)
2
−, (Cp = C
5H
5), Re(CO)
5
−1, Mn(CO)
5
−, CpW(CO)
3
−1, CpMo(CO)
3
− with 2-(pentacarbonylmagnanese)-4,6-difluoro-1,3,5-triazine. The observed trends substantiate the hypothesis of enhanced reactivity of contact ion pairs as compared to solvent-separated ion pairs and free ions.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/0022-328X(87)80309-1</doi><tpages>6</tpages></addata></record> |
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| identifier | ISSN: 0022-328X |
| ispartof | Journal of organometallic chemistry, 1987-04, Vol.321 (3), p.371-376 |
| issn | 0022-328X 1872-8561 |
| language | eng |
| recordid | cdi_pascalfrancis_primary_8082530 |
| source | Access via ScienceDirect (Elsevier) |
| subjects | Chemistry Exact sciences and technology Inorganic chemistry and origins of life Kinetics and mechanism of reactions |
| title | Transition metal carbonylates in nucleophilic aromatic substitution: II. Medium effects for substitution in 2-(pentacarbonylmanganese)-4,6-difluoro-1,3,5-triazine |
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