Topotaxy between BaTiO3 and Ba6Ti17O40

The orientational relationship between intergrown lamellae of tetragonal (t) BaTiO3 and monoclinic (m) Ba6Ti17O40 was found to be (111)t||(001)m, (001)t||(101)m, and [110]t||[010]m. On the basis of this relationship a model of a topotactic boundary between these two phases was constructed.

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Veröffentlicht in:Journal of the American Ceramic Society 1987-08, Vol.70 (8), p.C-193-C-195
Hauptverfasser: Kraševec, Viktor, Drofenik, Miha, Kolar, Drogo
Format: Artikel
Sprache:eng
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Zusammenfassung:The orientational relationship between intergrown lamellae of tetragonal (t) BaTiO3 and monoclinic (m) Ba6Ti17O40 was found to be (111)t||(001)m, (001)t||(101)m, and [110]t||[010]m. On the basis of this relationship a model of a topotactic boundary between these two phases was constructed.
ISSN:0002-7820
1551-2916
DOI:10.1111/j.1151-2916.1987.tb05723.x