Reactivity of cationic molybdenum(II) complexes. I: Hydride reduction of the 18 electron complexes [Mo(CO)3(η-C5Me5)L]+ [L= PPh3 or P(OMe)3] and isolation of the thermally stable formyl complex cis-[Mo(CO)2(η-C5Me5)-{P(OMe)3}(CHO)]. Crystal structure of [Mo(CO)3(η-C5Me5)(PPh3)]BF4•0.5MeOH

Reactivity of cationic molybdenum(II) complexes. I: Hydride reduction of the 18 electron complexes [Mo(CO)3(η-C5Me5)L]+ [L= PPh3 or P(OMe)3] and isolation of the thermally stable formyl complex cis-[Mo(CO)2(η-C5Me5)-{P(OMe)3}(CHO)]. Crystal structure of [Mo(CO)3(η-C5Me5)(PPh3)]BF4•0.5MeOH

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Veröffentlicht in:Journal of the Chemical Society. Dalton transactions 1988 (2), p.329-333
Hauptverfasser: LEONI, P, AQUILINI, E, PASQUALI, M, MARCHETTI, F, SABAT, M
Format: Artikel
Sprache:eng
Schlagworte:
Carbonyl and nitrosyl compounds, and their complexes
Carbonyl and nitrosyl metals
Chemistry
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Inorganic chemistry and origins of life
Inorganic compounds
Physics
Preparations and properties
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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ISSN:0300-9246
2050-5671