Influence of Thermoactivated Molecular Motions on the 35Cl Quadrupole Relaxation

The effect on the Cl quadrupole relaxation of modulations of the electric field gradient by thermally activated motions of nearby nonbonding symmetric and asymmetric atomic groups has been investigated. This way the activation energy of the motions has been determined and the fraction of the electri...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	Zeitschrift für Naturforschung. A, A Journal of physical sciences A Journal of physical sciences, 1990-04, Vol.45 (3), p.531-535
Hauptverfasser:	Kjuntsel, I.A., Mokeeva, V. A., Shaposhnikov, I. G., Soifer, G. B.
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic and molecular physics Exact sciences and technology Modulation effect Molecular motion Molecular properties and interactions with photons Nuclear quadrupole relaxation Physics
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

Beschreibung
Zusammenfassung:	The effect on the Cl quadrupole relaxation of modulations of the electric field gradient by thermally activated motions of nearby nonbonding symmetric and asymmetric atomic groups has been investigated. This way the activation energy of the motions has been determined and the fraction of the electric field gradient influenced by the motions has been estimated. This fraction can be taken as a measure of the intensity of nonbonding interactions in solids.
ISSN:	0932-0784 1865-7109
DOI:	10.1515/zna-1990-3-455