Cu(II) catalyzed hydrolysis of an unactivated ester based on reversible conjugate addition

Cu(II) catalyzed hydrolysis of an unactivated ester based on reversible conjugate addition

Cu(II) catalysis provides a 16,000-fold acceleration in the hydrolysis of methyl acrylate when a removable vicinal diamine ligand is used to increase the stability of the required copper chelate. Cu(II) provides a 16,000-fold acceleration in the hydrolysis of methyl acrylate when a removable ligand...

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Veröffentlicht in:Tetrahedron letters 1989, Vol.30 (50), p.6951-6954
Hauptverfasser: Duerr, Brook F., Czarnik, Anthony W.
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Sprache:eng
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Chemistry
Exact sciences and technology
Kinetics and mechanisms
Organic chemistry
Reactivity and mechanisms
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container_title Tetrahedron letters
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creator Duerr, Brook F.
Czarnik, Anthony W.
description Cu(II) catalysis provides a 16,000-fold acceleration in the hydrolysis of methyl acrylate when a removable vicinal diamine ligand is used to increase the stability of the required copper chelate. Cu(II) provides a 16,000-fold acceleration in the hydrolysis of methyl acrylate when a removable ligand is used to increase the stability of the required copper chelate. Metal ion catalysis, not promotion, is observed.
doi_str_mv 10.1016/S0040-4039(01)93395-7
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subjects Chemistry
Exact sciences and technology
Kinetics and mechanisms
Organic chemistry
Reactivity and mechanisms
title Cu(II) catalyzed hydrolysis of an unactivated ester based on reversible conjugate addition
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