Microbiological synthesis of optically active (2R,3S)-2,3-deuteriocyclohexan-1-ones and (2R,3S)-2-methyl-3-deuteriocyclohexan-1-one. Enantiospecific anti-addition of hydrogen to the double bond of cyclohex-2-en-1-ones

Addition of hydrogen to the double bond of cyclohexenones during microbiological reduction by Beauveria sulfurescens gives the trans product in high yield (90%) resulting from anti-addition to the si face on C-2 and the re face on C-3. [Display omitted] [Display omitted] [Display omitted]

Bibliographische Detailangaben

Veröffentlicht in:	Tetrahedron: asymmetry 1992, Vol.3 (5), p.595-598
Hauptverfasser:	Dauphin, Ge´rard, Gourcy, Jean-Gabriel, Veschambre, Henri
Format:	Artikel
Sprache:	eng
Schlagworte:	Biological and medical sciences Fundamental and applied biological sciences. Psychology Growth, nutrition, metabolism, transports, enzymes. Molecular biology Microbiology Mycology
Online-Zugang:	Volltext
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