Microbiological synthesis of optically active (2R,3S)-2,3-deuteriocyclohexan-1-ones and (2R,3S)-2-methyl-3-deuteriocyclohexan-1-one. Enantiospecific anti-addition of hydrogen to the double bond of cyclohex-2-en-1-ones
Addition of hydrogen to the double bond of cyclohexenones during microbiological reduction by Beauveria sulfurescens gives the trans product in high yield (90%) resulting from anti-addition to the si face on C-2 and the re face on C-3. [Display omitted] [Display omitted] [Display omitted]
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| Veröffentlicht in: | Tetrahedron: asymmetry 1992, Vol.3 (5), p.595-598 |
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| container_end_page | 598 |
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| container_issue | 5 |
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| container_title | Tetrahedron: asymmetry |
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| creator | Dauphin, Ge´rard Gourcy, Jean-Gabriel Veschambre, Henri |
| description | Addition of hydrogen to the double bond of cyclohexenones during microbiological reduction by
Beauveria sulfurescens gives the
trans product in high yield (90%) resulting from
anti-addition to the
si face on C-2 and the
re face on C-3.
[Display omitted]
[Display omitted]
[Display omitted] |
| doi_str_mv | 10.1016/S0957-4166(00)82289-2 |
| format | Article |
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Beauveria sulfurescens gives the
trans product in high yield (90%) resulting from
anti-addition to the
si face on C-2 and the
re face on C-3.
[Display omitted]
[Display omitted]
[Display omitted]</description><identifier>ISSN: 0957-4166</identifier><identifier>EISSN: 1362-511X</identifier><identifier>DOI: 10.1016/S0957-4166(00)82289-2</identifier><language>eng</language><publisher>Oxford: Elsevier Ltd</publisher><subject>Biological and medical sciences ; Fundamental and applied biological sciences. Psychology ; Growth, nutrition, metabolism, transports, enzymes. Molecular biology ; Microbiology ; Mycology</subject><ispartof>Tetrahedron: asymmetry, 1992, Vol.3 (5), p.595-598</ispartof><rights>1992 Pergamon Press Ltd</rights><rights>1992 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0957416600822892$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,4010,27900,27901,27902,65306</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=5338816$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>Dauphin, Ge´rard</creatorcontrib><creatorcontrib>Gourcy, Jean-Gabriel</creatorcontrib><creatorcontrib>Veschambre, Henri</creatorcontrib><title>Microbiological synthesis of optically active (2R,3S)-2,3-deuteriocyclohexan-1-ones and (2R,3S)-2-methyl-3-deuteriocyclohexan-1-one. Enantiospecific anti-addition of hydrogen to the double bond of cyclohex-2-en-1-ones</title><title>Tetrahedron: asymmetry</title><description>Addition of hydrogen to the double bond of cyclohexenones during microbiological reduction by
Beauveria sulfurescens gives the
trans product in high yield (90%) resulting from
anti-addition to the
si face on C-2 and the
re face on C-3.
[Display omitted]
[Display omitted]
[Display omitted]</description><subject>Biological and medical sciences</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>Growth, nutrition, metabolism, transports, enzymes. Molecular biology</subject><subject>Microbiology</subject><subject>Mycology</subject><issn>0957-4166</issn><issn>1362-511X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1992</creationdate><recordtype>article</recordtype><recordid>eNp1Ud1KHjEQDdKCn9pHKOTCCwWj-dlsslciYltBKdQWeheyyaxfZE0-NlG6j-rbNKtVr3o1zJkzZw5zEPrM6DGjrD25oZ1UpGFte0DpoeZcd4RvoRUTLSeSsd8f0OqNso12cr6jdU8yuUJP18FNqQ9pTLfB2RHnOZY15JBxGnDalAUcZ2xdCY-AD_iPI3FzSPiRIB4eCkwhudmNaQ1_bCSMpAgZ2-jfmeQeynoeyf8XjvFFtLGElDfgwhAcXjpivQ8VjIuR9eyndAsRl4SrPezTQz8C7lO9VMevivUavLrYQx8HO2b49K_uol9fLn6efyNX379enp9dEeBcFCIH32qlG97ozjUgG6m0aodOWa-VakWvrReq0cB63zPJBm57qixtOkU9pULsov0X3Y3N9VfDZKML2WymcG-n2UghtGZtpZ2-0KB6eQwwmewCRAc-TOCK8SkYRs0SqHkO1CxpGUrNc6CGi78wn5XJ</recordid><startdate>1992</startdate><enddate>1992</enddate><creator>Dauphin, Ge´rard</creator><creator>Gourcy, Jean-Gabriel</creator><creator>Veschambre, Henri</creator><general>Elsevier Ltd</general><general>Elsevier Science</general><scope>IQODW</scope></search><sort><creationdate>1992</creationdate><title>Microbiological synthesis of optically active (2R,3S)-2,3-deuteriocyclohexan-1-ones and (2R,3S)-2-methyl-3-deuteriocyclohexan-1-one. Enantiospecific anti-addition of hydrogen to the double bond of cyclohex-2-en-1-ones</title><author>Dauphin, Ge´rard ; Gourcy, Jean-Gabriel ; Veschambre, Henri</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-e223t-5fd687842489c4e5457876f97ad87763b8ad3748e1bdb151f2ab07a04970d0033</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1992</creationdate><topic>Biological and medical sciences</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>Growth, nutrition, metabolism, transports, enzymes. Molecular biology</topic><topic>Microbiology</topic><topic>Mycology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dauphin, Ge´rard</creatorcontrib><creatorcontrib>Gourcy, Jean-Gabriel</creatorcontrib><creatorcontrib>Veschambre, Henri</creatorcontrib><collection>Pascal-Francis</collection><jtitle>Tetrahedron: asymmetry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dauphin, Ge´rard</au><au>Gourcy, Jean-Gabriel</au><au>Veschambre, Henri</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Microbiological synthesis of optically active (2R,3S)-2,3-deuteriocyclohexan-1-ones and (2R,3S)-2-methyl-3-deuteriocyclohexan-1-one. Enantiospecific anti-addition of hydrogen to the double bond of cyclohex-2-en-1-ones</atitle><jtitle>Tetrahedron: asymmetry</jtitle><date>1992</date><risdate>1992</risdate><volume>3</volume><issue>5</issue><spage>595</spage><epage>598</epage><pages>595-598</pages><issn>0957-4166</issn><eissn>1362-511X</eissn><abstract>Addition of hydrogen to the double bond of cyclohexenones during microbiological reduction by
Beauveria sulfurescens gives the
trans product in high yield (90%) resulting from
anti-addition to the
si face on C-2 and the
re face on C-3.
[Display omitted]
[Display omitted]
[Display omitted]</abstract><cop>Oxford</cop><pub>Elsevier Ltd</pub><doi>10.1016/S0957-4166(00)82289-2</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0957-4166 |
| ispartof | Tetrahedron: asymmetry, 1992, Vol.3 (5), p.595-598 |
| issn | 0957-4166 1362-511X |
| language | eng |
| recordid | cdi_pascalfrancis_primary_5338816 |
| source | Elsevier ScienceDirect Journals |
| subjects | Biological and medical sciences Fundamental and applied biological sciences. Psychology Growth, nutrition, metabolism, transports, enzymes. Molecular biology Microbiology Mycology |
| title | Microbiological synthesis of optically active (2R,3S)-2,3-deuteriocyclohexan-1-ones and (2R,3S)-2-methyl-3-deuteriocyclohexan-1-one. Enantiospecific anti-addition of hydrogen to the double bond of cyclohex-2-en-1-ones |
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