STUDIES ON PHOSPHONIUM YLIDES XVII. THE BEHAVIOUR OF WITTIG REAGENTS TOWARD 1,4-NAPHTHOQUINONEMONOBENZENESULFONIMINE

Methylenetriphenylphosphoranes (IIa, b) react with 1,4-naphthoquinonemonobenzenesulfonimine (I) yielding the new azapropane adduct IIIa together with the dimeric adducts IIIb, IIIc, and IIId. Structures of the new products were established by analytical and spectroscopic (IR, 1 H NMR, 31 P NMR, 13 C...

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Veröffentlicht in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1991-10, Vol.62 (1-4), p.231-235
Hauptverfasser: Boulos, L. S., Zayed, M. F., El-khoshnieh, Y. O.
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container_end_page 235
container_issue 1-4
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container_title Phosphorus, sulfur, and silicon and the related elements
container_volume 62
creator Boulos, L. S.
Zayed, M. F.
El-khoshnieh, Y. O.
description Methylenetriphenylphosphoranes (IIa, b) react with 1,4-naphthoquinonemonobenzenesulfonimine (I) yielding the new azapropane adduct IIIa together with the dimeric adducts IIIb, IIIc, and IIId. Structures of the new products were established by analytical and spectroscopic (IR, 1 H NMR, 31 P NMR, 13 C NMR, and MS) results. A mechanism is proposed to explain the formation of compounds III.
doi_str_mv 10.1080/10426509108034481
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identifier ISSN: 1042-6507
ispartof Phosphorus, sulfur, and silicon and the related elements, 1991-10, Vol.62 (1-4), p.231-235
issn 1042-6507
1563-5325
language eng
recordid cdi_pascalfrancis_primary_5162489
source Taylor & Francis:Master (3349 titles)
subjects 1,4-Naphthoquinonemonobenzenesulfonimine (I)
Carbethoxymethylenetriphenylphosphorane (IIb)
Carbmethoxymethylenetriphenylphosphorane (IIa)
Chemistry
Exact sciences and technology
Organic chemistry
Organometalloidal and organometallic compounds
P derivatives
Preparations and properties
the dimeric products IIIb, IIIc and IIId
the new azapropane adduct IIIa
title STUDIES ON PHOSPHONIUM YLIDES XVII. THE BEHAVIOUR OF WITTIG REAGENTS TOWARD 1,4-NAPHTHOQUINONEMONOBENZENESULFONIMINE
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