Revised 13C Nmr Assignments for Norditerpenoid Alkaloids with 7,8-Methylenedioxy and 10β-OH Groups

13C-nmr chemical shift assignments for the norditerpenoid alkaloids deltaline [1], deltamine [2], dictyocarpine [3], and 14-acetyldictyocarpine [5] have been revised on the basis of a study of their 1D, 2D, and selective INEPT nmr spectra. These revisions suggest that the 13C-nmr chemical shift assi...

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Veröffentlicht in:Journal of natural products (Washington, D.C.) D.C.), 1993-07, Vol.56 (7), p.1140-1147
Hauptverfasser: Desai, Haridutt K, Pelletier, W. William
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Pelletier, W. William
description 13C-nmr chemical shift assignments for the norditerpenoid alkaloids deltaline [1], deltamine [2], dictyocarpine [3], and 14-acetyldictyocarpine [5] have been revised on the basis of a study of their 1D, 2D, and selective INEPT nmr spectra. These revisions suggest that the 13C-nmr chemical shift assignments for twenty-eight other norditerpenoid alkaloids possessing 7,8-methylenedioxy and 10 beta-OH groups may have to be revised. Complete 1H-nmr chemical shift assignments for compounds 1-3 and 5 are also reported
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subjects ALCALOIDE
ALCALOIDES
Analytical, structural and metabolic biochemistry
Biological and medical sciences
DELPHINIUM
DITERPENOIDE
DITERPENOS
ESPECTROSCOPIA RMN
Fundamental and applied biological sciences. Psychology
Other biological molecules
SPECTROSCOPIE RMN
Terpenes, steroids. Hormones
title Revised 13C Nmr Assignments for Norditerpenoid Alkaloids with 7,8-Methylenedioxy and 10β-OH Groups
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