Revised 13C Nmr Assignments for Norditerpenoid Alkaloids with 7,8-Methylenedioxy and 10β-OH Groups
13C-nmr chemical shift assignments for the norditerpenoid alkaloids deltaline [1], deltamine [2], dictyocarpine [3], and 14-acetyldictyocarpine [5] have been revised on the basis of a study of their 1D, 2D, and selective INEPT nmr spectra. These revisions suggest that the 13C-nmr chemical shift assi...
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Veröffentlicht in: | Journal of natural products (Washington, D.C.) D.C.), 1993-07, Vol.56 (7), p.1140-1147 |
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creator | Desai, Haridutt K Pelletier, W. William |
description | 13C-nmr chemical shift assignments for the norditerpenoid alkaloids deltaline [1], deltamine [2], dictyocarpine [3], and 14-acetyldictyocarpine [5] have been revised on the basis of a study of their 1D, 2D, and selective INEPT nmr spectra. These revisions suggest that the 13C-nmr chemical shift assignments for twenty-eight other norditerpenoid alkaloids possessing 7,8-methylenedioxy and 10 beta-OH groups may have to be revised. Complete 1H-nmr chemical shift assignments for compounds 1-3 and 5 are also reported |
doi_str_mv | 10.1021/np50097a019 |
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William</creator><creatorcontrib>Desai, Haridutt K ; Pelletier, W. William</creatorcontrib><description>13C-nmr chemical shift assignments for the norditerpenoid alkaloids deltaline [1], deltamine [2], dictyocarpine [3], and 14-acetyldictyocarpine [5] have been revised on the basis of a study of their 1D, 2D, and selective INEPT nmr spectra. These revisions suggest that the 13C-nmr chemical shift assignments for twenty-eight other norditerpenoid alkaloids possessing 7,8-methylenedioxy and 10 beta-OH groups may have to be revised. Complete 1H-nmr chemical shift assignments for compounds 1-3 and 5 are also reported</description><identifier>ISSN: 0163-3864</identifier><identifier>EISSN: 1520-6025</identifier><identifier>DOI: 10.1021/np50097a019</identifier><identifier>CODEN: JNPRDF</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>ALCALOIDE ; ALCALOIDES ; Analytical, structural and metabolic biochemistry ; Biological and medical sciences ; DELPHINIUM ; DITERPENOIDE ; DITERPENOS ; ESPECTROSCOPIA RMN ; Fundamental and applied biological sciences. Psychology ; Other biological molecules ; SPECTROSCOPIE RMN ; Terpenes, steroids. 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William</creatorcontrib><title>Revised 13C Nmr Assignments for Norditerpenoid Alkaloids with 7,8-Methylenedioxy and 10β-OH Groups</title><title>Journal of natural products (Washington, D.C.)</title><addtitle>J. Nat. Prod</addtitle><description>13C-nmr chemical shift assignments for the norditerpenoid alkaloids deltaline [1], deltamine [2], dictyocarpine [3], and 14-acetyldictyocarpine [5] have been revised on the basis of a study of their 1D, 2D, and selective INEPT nmr spectra. These revisions suggest that the 13C-nmr chemical shift assignments for twenty-eight other norditerpenoid alkaloids possessing 7,8-methylenedioxy and 10 beta-OH groups may have to be revised. Complete 1H-nmr chemical shift assignments for compounds 1-3 and 5 are also reported</description><subject>ALCALOIDE</subject><subject>ALCALOIDES</subject><subject>Analytical, structural and metabolic biochemistry</subject><subject>Biological and medical sciences</subject><subject>DELPHINIUM</subject><subject>DITERPENOIDE</subject><subject>DITERPENOS</subject><subject>ESPECTROSCOPIA RMN</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>Other biological molecules</subject><subject>SPECTROSCOPIE RMN</subject><subject>Terpenes, steroids. 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William</creator><general>American Chemical Society</general><general>American Society of Pharmacognosy</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope></search><sort><creationdate>19930701</creationdate><title>Revised 13C Nmr Assignments for Norditerpenoid Alkaloids with 7,8-Methylenedioxy and 10β-OH Groups</title><author>Desai, Haridutt K ; Pelletier, W. William</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a1186-b3f95b2ba662bbd203fab8f7423508d5a93eca4c852380f87876d85224b60f643</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1993</creationdate><topic>ALCALOIDE</topic><topic>ALCALOIDES</topic><topic>Analytical, structural and metabolic biochemistry</topic><topic>Biological and medical sciences</topic><topic>DELPHINIUM</topic><topic>DITERPENOIDE</topic><topic>DITERPENOS</topic><topic>ESPECTROSCOPIA RMN</topic><topic>Fundamental and applied biological sciences. Psychology</topic><topic>Other biological molecules</topic><topic>SPECTROSCOPIE RMN</topic><topic>Terpenes, steroids. Hormones</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Desai, Haridutt K</creatorcontrib><creatorcontrib>Pelletier, W. William</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><jtitle>Journal of natural products (Washington, D.C.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Desai, Haridutt K</au><au>Pelletier, W. William</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Revised 13C Nmr Assignments for Norditerpenoid Alkaloids with 7,8-Methylenedioxy and 10β-OH Groups</atitle><jtitle>Journal of natural products (Washington, D.C.)</jtitle><addtitle>J. Nat. Prod</addtitle><date>1993-07-01</date><risdate>1993</risdate><volume>56</volume><issue>7</issue><spage>1140</spage><epage>1147</epage><pages>1140-1147</pages><issn>0163-3864</issn><eissn>1520-6025</eissn><coden>JNPRDF</coden><abstract>13C-nmr chemical shift assignments for the norditerpenoid alkaloids deltaline [1], deltamine [2], dictyocarpine [3], and 14-acetyldictyocarpine [5] have been revised on the basis of a study of their 1D, 2D, and selective INEPT nmr spectra. These revisions suggest that the 13C-nmr chemical shift assignments for twenty-eight other norditerpenoid alkaloids possessing 7,8-methylenedioxy and 10 beta-OH groups may have to be revised. Complete 1H-nmr chemical shift assignments for compounds 1-3 and 5 are also reported</abstract><cop>Washington, DC</cop><cop>Glendale, AZ</cop><pub>American Chemical Society</pub><doi>10.1021/np50097a019</doi><tpages>8</tpages></addata></record> |
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subjects | ALCALOIDE ALCALOIDES Analytical, structural and metabolic biochemistry Biological and medical sciences DELPHINIUM DITERPENOIDE DITERPENOS ESPECTROSCOPIA RMN Fundamental and applied biological sciences. Psychology Other biological molecules SPECTROSCOPIE RMN Terpenes, steroids. Hormones |
title | Revised 13C Nmr Assignments for Norditerpenoid Alkaloids with 7,8-Methylenedioxy and 10β-OH Groups |
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