Revised 13C Nmr Assignments for Norditerpenoid Alkaloids with 7,8-Methylenedioxy and 10β-OH Groups

13C-nmr chemical shift assignments for the norditerpenoid alkaloids deltaline [1], deltamine [2], dictyocarpine [3], and 14-acetyldictyocarpine [5] have been revised on the basis of a study of their 1D, 2D, and selective INEPT nmr spectra. These revisions suggest that the 13C-nmr chemical shift assi...

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Veröffentlicht in:Journal of natural products (Washington, D.C.) D.C.), 1993-07, Vol.56 (7), p.1140-1147
Hauptverfasser: Desai, Haridutt K, Pelletier, W. William
Format: Artikel
Sprache:eng
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Zusammenfassung:13C-nmr chemical shift assignments for the norditerpenoid alkaloids deltaline [1], deltamine [2], dictyocarpine [3], and 14-acetyldictyocarpine [5] have been revised on the basis of a study of their 1D, 2D, and selective INEPT nmr spectra. These revisions suggest that the 13C-nmr chemical shift assignments for twenty-eight other norditerpenoid alkaloids possessing 7,8-methylenedioxy and 10 beta-OH groups may have to be revised. Complete 1H-nmr chemical shift assignments for compounds 1-3 and 5 are also reported
ISSN:0163-3864
1520-6025
DOI:10.1021/np50097a019