Fullerene Sugars: Preparation of Enantiomerically Pure, Spiro-Linked C-Glycosides of C60

“Sweetened buckyballs” are prepared in good yields. The C‐glycosylated, uniform, enantiomerically pure C60 monoaddition products 1 (R = benzyl, pivaloyl) are differentiated not only by their chi‐roptical properties, but also by the conformation of the glycosyl residue, which is dependent on its subs...

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Veröffentlicht in:	Angewandte Chemie (International ed.) 1992-10, Vol.31 (10), p.1388-1390
Hauptverfasser:	Vasella, Andrea, Uhlmann, Peter, Waldraff, Christian A. A., Diederich, François, Thilgen, Carlo
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbohydrates with 4, 5, 6, ... C atoms, dissacharides and oligosaccharides Carbohydrates. Nucleosides and nucleotides Chemistry Exact sciences and technology Organic chemistry Preparations and properties
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	“Sweetened buckyballs” are prepared in good yields. The C‐glycosylated, uniform, enantiomerically pure C60 monoaddition products 1 (R = benzyl, pivaloyl) are differentiated not only by their chi‐roptical properties, but also by the conformation of the glycosyl residue, which is dependent on its substituents.
ISSN:	0570-0833 1521-3773
DOI:	10.1002/anie.199213881