A NEWLY DEVISED METHOD FOR THE OXIDATIVE UNMASKING OF 1, N6-ETHENO-ADENOSINES : FACILE CONVERSION OF ADENOSINE INTO 2-DEUTERATED ADENOSINE

2-Deuterated adenosine (5) was conveniently prepared from adenosine (1) by applying the ring-fission and reclosure methodology of 1, N6-ethenoadenosine (2) and a new oxidative unmasking method of the etheno moiety.

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Veröffentlicht in:Chemical & pharmaceutical bulletin 1992/06/25, Vol.40(6), pp.1656-1658
Hauptverfasser: SAKO, Magoichi, HAYASHI, Toru, HIROTA, Kosaku, MAKI, Yoshifumi
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container_end_page 1658
container_issue 6
container_start_page 1656
container_title Chemical & pharmaceutical bulletin
container_volume 40
creator SAKO, Magoichi
HAYASHI, Toru
HIROTA, Kosaku
MAKI, Yoshifumi
description 2-Deuterated adenosine (5) was conveniently prepared from adenosine (1) by applying the ring-fission and reclosure methodology of 1, N6-ethenoadenosine (2) and a new oxidative unmasking method of the etheno moiety.
doi_str_mv 10.1248/cpb.40.1656
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subjects 1, N6-ethenoadenosine
2-deuterated adenosine
adenosine
Carbohydrates. Nucleosides and nucleotides
Chemistry
Exact sciences and technology
Nucleosides, nucleotides and oligonucleotides
Organic chemistry
oxidative unmasking
Preparations and properties
title A NEWLY DEVISED METHOD FOR THE OXIDATIVE UNMASKING OF 1, N6-ETHENO-ADENOSINES : FACILE CONVERSION OF ADENOSINE INTO 2-DEUTERATED ADENOSINE
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