A NEWLY DEVISED METHOD FOR THE OXIDATIVE UNMASKING OF 1, N6-ETHENO-ADENOSINES : FACILE CONVERSION OF ADENOSINE INTO 2-DEUTERATED ADENOSINE

2-Deuterated adenosine (5) was conveniently prepared from adenosine (1) by applying the ring-fission and reclosure methodology of 1, N6-ethenoadenosine (2) and a new oxidative unmasking method of the etheno moiety.

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Bibliographische Detailangaben
Veröffentlicht in:	Chemical & pharmaceutical bulletin 1992/06/25, Vol.40(6), pp.1656-1658
Hauptverfasser:	SAKO, Magoichi, HAYASHI, Toru, HIROTA, Kosaku, MAKI, Yoshifumi
Format:	Artikel
Sprache:	eng
Schlagworte:	1, N6-ethenoadenosine 2-deuterated adenosine adenosine Carbohydrates. Nucleosides and nucleotides Chemistry Exact sciences and technology Nucleosides, nucleotides and oligonucleotides Organic chemistry oxidative unmasking Preparations and properties
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Beschreibung
Zusammenfassung:	2-Deuterated adenosine (5) was conveniently prepared from adenosine (1) by applying the ring-fission and reclosure methodology of 1, N6-ethenoadenosine (2) and a new oxidative unmasking method of the etheno moiety.
ISSN:	0009-2363 1347-5223
DOI:	10.1248/cpb.40.1656