A New Approach to the Ribosylribitol Intermediate for the Synthesis of Haemophilus Influenzae Type B Oligosaccharides

A New Approach to the Ribosylribitol Intermediate for the Synthesis of Haemophilus Influenzae Type B Oligosaccharides

The 3-o-allyl-2,5-di-o-benzoyl-β-d-ribofuranosyl trichloroacetimidate 9 was obtained in good yield after eleven steps from glucose. This imidate has proved to be an excellent precursor for the synthesis of ribosylribitol 13, which is the key monomer unit for the synthesis of Haemophilus influenzae t...

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Veröffentlicht in:Journal of carbohydrate chemistry 1994-04, Vol.13 (3), p.465-474
Hauptverfasser: Machado, Ivan Chiu, Alonso, Odalys Madrazo, Bencomo, Vicente Verez
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Sprache:eng
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Carbohydrates with 4, 5, 6, ... C atoms, dissacharides and oligosaccharides
Carbohydrates. Nucleosides and nucleotides
Chemistry
Exact sciences and technology
Organic chemistry
Preparations and properties
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container_end_page 474
container_issue 3
container_start_page 465
container_title Journal of carbohydrate chemistry
container_volume 13
creator Machado, Ivan Chiu
Alonso, Odalys Madrazo
Bencomo, Vicente Verez
description The 3-o-allyl-2,5-di-o-benzoyl-β-d-ribofuranosyl trichloroacetimidate 9 was obtained in good yield after eleven steps from glucose. This imidate has proved to be an excellent precursor for the synthesis of ribosylribitol 13, which is the key monomer unit for the synthesis of Haemophilus influenzae type b PRP oligosaccharides.
doi_str_mv 10.1080/07328309408009207
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source Taylor & Francis:Master (3349 titles)
subjects Carbohydrates with 4, 5, 6, ... C atoms, dissacharides and oligosaccharides
Carbohydrates. Nucleosides and nucleotides
Chemistry
Exact sciences and technology
Organic chemistry
Preparations and properties
title A New Approach to the Ribosylribitol Intermediate for the Synthesis of Haemophilus Influenzae Type B Oligosaccharides
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