A New Approach to the Ribosylribitol Intermediate for the Synthesis of Haemophilus Influenzae Type B Oligosaccharides

The 3-o-allyl-2,5-di-o-benzoyl-β-d-ribofuranosyl trichloroacetimidate 9 was obtained in good yield after eleven steps from glucose. This imidate has proved to be an excellent precursor for the synthesis of ribosylribitol 13, which is the key monomer unit for the synthesis of Haemophilus influenzae t...

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Veröffentlicht in:	Journal of carbohydrate chemistry 1994-04, Vol.13 (3), p.465-474
Hauptverfasser:	Machado, Ivan Chiu, Alonso, Odalys Madrazo, Bencomo, Vicente Verez
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbohydrates with 4, 5, 6, ... C atoms, dissacharides and oligosaccharides Carbohydrates. Nucleosides and nucleotides Chemistry Exact sciences and technology Organic chemistry Preparations and properties
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The 3-o-allyl-2,5-di-o-benzoyl-β-d-ribofuranosyl trichloroacetimidate 9 was obtained in good yield after eleven steps from glucose. This imidate has proved to be an excellent precursor for the synthesis of ribosylribitol 13, which is the key monomer unit for the synthesis of Haemophilus influenzae type b PRP oligosaccharides.
ISSN:	0732-8303 1532-2327
DOI:	10.1080/07328309408009207