A Spectroscopic Study of Preferential Solvation of Fe(bipy)2(CN)2 in Binary Aqueous 2-Ethoxy Ethanol Mixtures

Preferential Solvation of bis-(2,2′-bipyridyl) biscyanoiron(II) was investigated in 2-ethoxy ethanol water binary aqueous mixtures. The treatment showed that preferential solvation by 2-ethoxy ethanol occurs. The preferential solvation constant at 298.15° K was found to be equal to (4.96 ± 0.06) and...

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Veröffentlicht in:	Spectroscopy letters 1994-03, Vol.27 (3), p.333-340
Hauptverfasser:	Shraydeh, Bassem F., Salih, Subhi
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic and molecular physics Exact sciences and technology Intensities and shapes of molecular spectral lines and bands Line and band widths, shapes, and shifts Molecular properties and interactions with photons Physics
Online-Zugang:	Volltext
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Zusammenfassung:	Preferential Solvation of bis-(2,2′-bipyridyl) biscyanoiron(II) was investigated in 2-ethoxy ethanol water binary aqueous mixtures. The treatment showed that preferential solvation by 2-ethoxy ethanol occurs. The preferential solvation constant at 298.15° K was found to be equal to (4.96 ± 0.06) and the free energy of preferential solvations ΔG has a value of 3.97° KJ mol −1
ISSN:	0038-7010 1532-2289
DOI:	10.1080/00387019408000848