Degradation Mechanism of Corrosion Resistance for Al-0.9 mass%Mg2Si Alloy with Ga

The effect of Ga content on the characteristics of precipitation for Al-0.9 mass%Mg2Si alloys was investigated by the measurements of DTA curves of aging, transmission electron microscopy, and electron diffraction of precipitates. Furthermore, the relationship between the precipitation behavior and corrosion resistance for the alloys was estimated by means of an electrochemical measurement of the polarization curves, immersed corrosion tests, and scanning electron microscopic observations of the corroded surfaces for the alloys with various phases in a dilute HClO4 solution. The main results obtained are summarized as follows: (1) The effect of the added Ga on the characteristics of precipitation occurs mainly in G.P. II zone, and its initiation temperature of Mg2Si precipitation is lowered with increasing Ga content in the alloys. However, the distribution and composition of precipitates with transition and equilibrium phases are independent of Ga content. (2) The activation potentials (Eact.) of Al-0.9 mass%Mg2Si alloys in a dilute HClO4 solution decrease in the order of super saturated solid solution>equilibrium phase>transition phase. On the contrary, the anodic current densities (log(Ia)) of the alloys under a potentiostatic condition increase in the order of super saturated solid solution