From Gas Phase to Condensed Phase: Towards Metaphosphate Generation in Solution

Based on attempts to generate methyl metaphophate in solution by thermal fragmentation of a cyclic pyrocarbonate phosphate, it has emerged that reaction of methyl dichlorophosphate with anhydrous potassium hydrogen carbonate serves as an alternative approach as proven by trapping with styrene oxide...

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Veröffentlicht in:	Phosphorus, sulfur and silicon and the related elements (Print) sulfur and silicon and the related elements (Print), 1993-03, Vol.76 (1-4), p.37-40
Hauptverfasser:	Banks, Malcolm R., Cadogan, J. I. G., Gosney, Ian, Hodgson, Philip K. G., Kilgour, Derek, Rodger, David R.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology Organic chemistry Organometalloidal and organometallic compounds P derivatives Preparations and properties
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Based on attempts to generate methyl metaphophate in solution by thermal fragmentation of a cyclic pyrocarbonate phosphate, it has emerged that reaction of methyl dichlorophosphate with anhydrous potassium hydrogen carbonate serves as an alternative approach as proven by trapping with styrene oxide to form a 1,3,2-dioxaphospholane.
ISSN:	1042-6507 1563-5325
DOI:	10.1080/10426509308032352