P...N Interaction and its Effect on the Structure and Properties of Phosphorylated α-Aminoketones Derivatives

P...N Interaction and its Effect on the Structure and Properties of Phosphorylated α-Aminoketones Derivatives

Reactions of α-aminoketones with P-chlorides in a basic medium are reported. Methods for the synthesis of Δ 4 -1,3,2-oxazahospholines and ß-amino of phosphorus from N to O and enamin-imine isomerization are discussed for the phosphorylated aminoketones. Nucleophylic and electrophylic reactivity of c...

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Veröffentlicht in:Phosphorus, sulfur and silicon and the related elements (Print) sulfur and silicon and the related elements (Print), 1993-02, Vol.75 (1-4), p.167-170
Hauptverfasser: Balitzky, Yuri V., Pipko, Serge E., Sinitsa, Anatoly D., Chernega, Alexander N., Gololobov, Yuri G., Nesmeyanov, A. N.
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Exact sciences and technology
Organic chemistry
Organometalloidal and organometallic compounds
P derivatives
Preparations and properties
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Zusammenfassung:Reactions of α-aminoketones with P-chlorides in a basic medium are reported. Methods for the synthesis of Δ 4 -1,3,2-oxazahospholines and ß-amino of phosphorus from N to O and enamin-imine isomerization are discussed for the phosphorylated aminoketones. Nucleophylic and electrophylic reactivity of cationes XV and XVI was studied.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426509308037391