β-Na3Hg: A Solid with a Quasi-Fluid Sodium Substructure between 36 and 60°C

β-Na3Hg: A Solid with a Quasi-Fluid Sodium Substructure between 36 and 60°C

The higher melting component of β‐Na3Hg, namely the Na atoms, are mobile in the solid at relatively low temperature (36–60 °C) throughout the range of existence of this structural modification. In contrast, the Hg atoms show no unusual mobility. β‐Na3Hg crystallizes in a distorted rhombohedral Li3Bi...

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Veröffentlicht in:Angewandte Chemie (International ed.) 1993-10, Vol.32 (10), p.1494-1495
Hauptverfasser: Deiseroth, Hans-Jörg, Rochnia, Matthias
Format: Artikel
Sprache:eng
Schlagworte:
Alloys
Applied sciences
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Metals. Metallurgy
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
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Beschreibung
Zusammenfassung:The higher melting component of β‐Na3Hg, namely the Na atoms, are mobile in the solid at relatively low temperature (36–60 °C) throughout the range of existence of this structural modification. In contrast, the Hg atoms show no unusual mobility. β‐Na3Hg crystallizes in a distorted rhombohedral Li3Bi‐type structure.
ISSN:0570-0833
1521-3773
DOI:10.1002/anie.199314941