The First Metal Complexes with a Doubly S3-Bridged Ferrocene Ligand
Bidentate coordination is observed with the sulfur‐bridged ferrocenophane 1: [Cu(CH3CN)4]BF4 and 1 react to form the salt [(1)2Cu]BF4. In the cation, the central copper atom is surrounded by a distorted tetrahedral arrangement of four sulfur atoms, each belonging to a different sulfur bridge.
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| Veröffentlicht in: | Angewandte Chemie (International ed.) 1994-09, Vol.33 (17), p.1752-1753 |
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| container_issue | 17 |
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| container_title | Angewandte Chemie (International ed.) |
| container_volume | 33 |
| creator | Ingham, Scott L. Long, Nicholas J. |
| description | Bidentate coordination is observed with the sulfur‐bridged ferrocenophane 1: [Cu(CH3CN)4]BF4 and 1 react to form the salt [(1)2Cu]BF4. In the cation, the central copper atom is surrounded by a distorted tetrahedral arrangement of four sulfur atoms, each belonging to a different sulfur bridge. |
| doi_str_mv | 10.1002/anie.199417521 |
| format | Article |
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| identifier | ISSN: 0570-0833 |
| ispartof | Angewandte Chemie (International ed.), 1994-09, Vol.33 (17), p.1752-1753 |
| issn | 0570-0833 1521-3773 |
| language | eng |
| recordid | cdi_pascalfrancis_primary_3409416 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Chemistry Condensed matter: structure, mechanical and thermal properties Coordination compounds Exact sciences and technology Inorganic chemistry and origins of life Inorganic compounds Metal complexes Physics Preparations and properties Structure of solids and liquids crystallography Structure of specific crystalline solids |
| title | The First Metal Complexes with a Doubly S3-Bridged Ferrocene Ligand |
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