The First Metal Complexes with a Doubly S3-Bridged Ferrocene Ligand

Bidentate coordination is observed with the sulfur‐bridged ferrocenophane 1: [Cu(CH3CN)4]BF4 and 1 react to form the salt [(1)2Cu]BF4. In the cation, the central copper atom is surrounded by a distorted tetrahedral arrangement of four sulfur atoms, each belonging to a different sulfur bridge.

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Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie (International ed.) 1994-09, Vol.33 (17), p.1752-1753
Hauptverfasser:	Ingham, Scott L., Long, Nicholas J.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Condensed matter: structure, mechanical and thermal properties Coordination compounds Exact sciences and technology Inorganic chemistry and origins of life Inorganic compounds Metal complexes Physics Preparations and properties Structure of solids and liquids crystallography Structure of specific crystalline solids
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Beschreibung
Zusammenfassung:	Bidentate coordination is observed with the sulfur‐bridged ferrocenophane 1: [Cu(CH3CN)4]BF4 and 1 react to form the salt [(1)2Cu]BF4. In the cation, the central copper atom is surrounded by a distorted tetrahedral arrangement of four sulfur atoms, each belonging to a different sulfur bridge.
ISSN:	0570-0833 1521-3773
DOI:	10.1002/anie.199417521