$Time-Resolved X-ray Diffraction Study of the Staging Phase Transition in CuCl2-Intercalated Graphite$

Time-Resolved X-ray Diffraction Study of the Staging Phase Transition in CuCl2-Intercalated Graphite

The staging phase transitions during deintercalation of CuCl2‐intercalated graphite have been studied using real‐time X‐ray powder diffraction. The evolution of the diffraction pattern observed during the deintercalation revealed gradual changes in phase composition. A detailed profile analysis enab...

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Veröffentlicht in:	Journal of applied crystallography 1995-02, Vol.28 (1), p.33-37
Hauptverfasser:	Van Malssen, K. F., Čapková, P., Schenk, H., Boehm, H. P.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Condensed matter: structure, mechanical and thermal properties Crystalline state (including molecular motions in solids) Crystallographic aspects of phase transformations pressure effects Exact sciences and technology Inorganic chemistry and origins of life Kinetics and mechanism of reactions Physics Structure of solids and liquids crystallography X-ray absorption spectroscopy: exafs, nexafs, xanes, etc X-ray diffraction and scattering
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Zusammenfassung:	The staging phase transitions during deintercalation of CuCl2‐intercalated graphite have been studied using real‐time X‐ray powder diffraction. The evolution of the diffraction pattern observed during the deintercalation revealed gradual changes in phase composition. A detailed profile analysis enabled a quantitative phase analysis and visualized the phase composition at any time during the reaction. Conclusions concerning the mechanism and kinetics of deintercalation are compared with theoretical results.
ISSN:	1600-5767 0021-8898 1600-5767
DOI:	10.1107/S0021889894007776