Superhard boron-rich borides and studies of the B C N system

The crystal chemistry of the B 4C-type structures is described. New structural data for B 12S, B 13Se and B 6O are presented. It is found that B 6O with a microhardness larger than that of B 4C invariably contains a high concentration of vacancies at the oxygen position (B 6O 1- x with x in the rang...

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Veröffentlicht in:Materials science & engineering. A, Structural materials : properties, microstructure and processing Structural materials : properties, microstructure and processing, 1996, Vol.209 (1), p.16-22
Hauptverfasser: Lundstro¨m, Torsten, Andreev, Yuri G.
Format: Artikel
Sprache:eng
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Zusammenfassung:The crystal chemistry of the B 4C-type structures is described. New structural data for B 12S, B 13Se and B 6O are presented. It is found that B 6O with a microhardness larger than that of B 4C invariably contains a high concentration of vacancies at the oxygen position (B 6O 1- x with x in the range 0.76–0.84). Structural results for graphite-like phases in the B-C-N system are presented and discussed.
ISSN:0921-5093
1873-4936
DOI:10.1016/0921-5093(95)10095-4