Superhard boron-rich borides and studies of the B C N system
The crystal chemistry of the B 4C-type structures is described. New structural data for B 12S, B 13Se and B 6O are presented. It is found that B 6O with a microhardness larger than that of B 4C invariably contains a high concentration of vacancies at the oxygen position (B 6O 1- x with x in the rang...
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Veröffentlicht in: | Materials science & engineering. A, Structural materials : properties, microstructure and processing Structural materials : properties, microstructure and processing, 1996, Vol.209 (1), p.16-22 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | The crystal chemistry of the B
4C-type structures is described. New structural data for B
12S, B
13Se and B
6O are presented. It is found that B
6O with a microhardness larger than that of B
4C invariably contains a high concentration of vacancies at the oxygen position (B
6O
1-
x
with
x in the range 0.76–0.84). Structural results for graphite-like phases in the B-C-N system are presented and discussed. |
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ISSN: | 0921-5093 1873-4936 |
DOI: | 10.1016/0921-5093(95)10095-4 |