Hydrogen/deuterium exchange during n-butane conversion on H-ZSM-5

The authors studied H/D exchange under conditions of conversion of n-butane over H-ZSN-5 zeolite. The H/D exchange rate was found to be at least one order of magnitude faster than dehydrogenation or catalytic cracking. 27 refs., 11 figs., 1 tab.

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Bibliographische Detailangaben
Veröffentlicht in:	Journal of Catalysis 1996-05, Vol.160 (2), p.183-189
Hauptverfasser:	NARBESHUBER, T. F, STOCKENHUBER, M, BRAIT, A, SESHAN, K, LERCHER, J. A
Format:	Artikel
Sprache:	eng
Schlagworte:	02 PETROLEUM 40 CHEMISTRY ALKENES BUTANE Catalysis Catalysts: preparations and properties CATALYTIC CRACKING CATALYTIC EFFECTS CHEMICAL REACTION KINETICS Chemistry DEHYDROGENATION DEUTERIUM Exact sciences and technology General and physical chemistry ISOTOPIC EXCHANGE TEMPERATURE DEPENDENCE TEMPERATURE RANGE 0400-1000 K Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry ZEOLITES
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Beschreibung
Zusammenfassung:	The authors studied H/D exchange under conditions of conversion of n-butane over H-ZSN-5 zeolite. The H/D exchange rate was found to be at least one order of magnitude faster than dehydrogenation or catalytic cracking. 27 refs., 11 figs., 1 tab.
ISSN:	0021-9517 1090-2694
DOI:	10.1006/jcat.1996.0137